"Critical mass" implies 100% purity. In a chain reaction, the density of the fissile material greatly influences the actual mass needed. If you could compress the 235U with enough force from a conventional explosion, to reduce the volume in half, you'd need less than 1/2 the mass. The relative abundance of fissile material 235U/238U in nuclear reactors precludes a nuclear explosion from occuring. It's not physically possible.